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Selective liquid-liquid extraction of molybdenum (VI) and

Jan 01, 2020 Selective liquid-liquid extraction of molybdenum (VI) and rhenium (VII) from a synthetic pregnant leach solution: Comparison between extractants and diluents Author links open overlay panel E. Quijada-Maldonado a A. Allain a B. Pérez a G. Merlet a R. Cabezas a R. Tapia b J. Romero a

US4026988A Selective extraction of molybdenum from

Molybdenum is selectively extracted from an aqueous solution containing various other metal values, e.g. copper, arsenic, iron, bismuth, antimony, tin, and lead in addition to molybdenum. The molybdenum-bearing solution is adjusted to a pH of about 2.0 or less, and, then, intimately contacted with an organic extracting solution containing an alpha-hydroxy oxime.

US4666685A Selective extraction of molybdenum and

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic Download PDF Info Publication number US4666685A. US4666685A US06/861,689 US86168986A US4666685A US 4666685 A US4666685 A US 4666685A US 86168986 A US86168986 A US 86168986A US 4666685 A US4666685 A US 4666685A

Selective Recovery of Molybdenum over Rhenium from

Abstract: Selective solvent extraction of molybdenum over rhenium from molybdenite (MoS2) flue dust leaching solution was studied. In the present work, thermodynamic calculations of the chemical equilibria in aqueous solution were first performed, and the

Extraction of molybdenum as an added value in steel

In the second step, a selective leaching of molybdenum was designed and tested. Step 2 showed that molybdenum can be efficiently leached with a low concentration of hydroxide and that the liquid does not need to be heated. After leaching, molybdenum can be separated from contaminating metals, mainly zinc, with conventional liquid extraction.

Selective extraction of molybdenum and vanadium from spent

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic . United States Patent 4666685 . Abstract: Spent hydrodesulfurization catalysts containing alumina, at least one metal from the group consisting of molybdenum, tungsten and vanadium and at least one metal from the group

Method of extraction of molybdenum from molybdenum

FIELD: petrochemical industry; methods of the selective extraction of molybdenum from the solutions containing molybdenum and vanadium. SUBSTANCE: the invention is pertaining to the method of the selective extraction of molybdenum from the liquid mixtures, in which molybdenum is present with vanadium at the amount of molybdenum exceeding (200) mg/l.

(PDF) Thiophosphinic acids as selective extractants for

By considering the selective extraction of molybdenum from tungsten, the extraction parameters and synergistic enhancement factor were interpreted at the batch experiments. In the column

Solvent extraction separation of molybdenum as thio

Dec 01, 2017 This was due to selective extraction of MoS 4 2 The percentage extraction of molybdenum increased from 27.6 to 98% and tungsten from 0.3 to 5% with increasing extractant concentration from 0.5 to 3% . The corresponding ß value varied from 137.1 to 924.4. Further increase of extractant concentration from 5 to 8%, Mo extraction increased

Mechanism of Selective Precipitation of Molybdenum from

Selective precipitation of molybdenum (Mo) is a widely utilized method for separation of Mo from tungstate solution; however, the corresponding mechanism is still unclear.

US4666685A Selective extraction of molybdenum and

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic Download PDF Info Publication number US4666685A. US4666685A US06/861,689 US86168986A US4666685A US 4666685 A US4666685 A US 4666685A US 86168986 A US86168986 A US 86168986A US 4666685 A US4666685 A US 4666685A

Selective extraction of molybdenum from copper concentrate

Request PDF Selective extraction of molybdenum from copper concentrate by air oxidation in alkaline solution Alkaline leaching of copper concentrate bearing molybdenite was investigated.

US2079805A Process for extracting molybdenum from

US2079805A US729766A US72976634A US2079805A US 2079805 A US2079805 A US 2079805A US 729766 A US729766 A US 729766A US 72976634 A US72976634 A US 72976634A US 2079805 A US2079805 A US 2079805A Authority US United States Prior art keywords ore solution sodium molybdenum wulfenite Prior art date 1934-06-09 Legal status (The legal status is an assumption and

extraction of molybdenum

May 30, 2013· A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni–Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 (D2EHPA) is an effective extractant for the extraction of molybdenum. The extraction of Mo is more than 90 % at pH

(PDF) Thiophosphinic acids as selective extractants for

By considering the selective extraction of molybdenum from tungsten, the extraction parameters and synergistic enhancement factor were interpreted at the batch experiments. In the column

Method of extraction of molybdenum from molybdenum

FIELD: petrochemical industry; methods of the selective extraction of molybdenum from the solutions containing molybdenum and vanadium. SUBSTANCE: the invention is pertaining to the method of the selective extraction of molybdenum from the liquid mixtures, in which molybdenum is present with vanadium at the amount of molybdenum exceeding (200) mg/l.

Mechanism of Selective Precipitation of Molybdenum from

Selective precipitation of molybdenum (Mo) is a widely utilized method for separation of Mo from tungstate solution; however, the corresponding mechanism is still unclear.

SPECTROPHOTOMETRIC DETERMINATION OF MOLYBDENUM IN

INTRODUCTION: Molybdenum is the one utmost important element for many organisms and has a wide distribution throughout nature 1.Molybdenum is a bio-essential element and its occurrence in water samples is of interest from both environmental and chemical points of view 2.. Molybdenum is commercially important in metallurgical and agricultural laboratories.

Separation of vanadium and molybdenum from aqueous

Oct 24, 2019 The separation of vanadium (V) and molybdenum (VI) was studied by co-extraction with an aqueous two-phase system formed by PEG2000 + sodium sulfate + water and by selective stripping with another aqueous two-phase system formed by ammonium sulfate solution and PEG2000 phase loaded vanadium and molybdenum. The effect of aqueous pH, concentration of vanadium and molybdenum

Molybdenum Metallurgy Review: Hydrometallurgical Routes to

Jan 30, 2014 Solvent extraction is highly selective for recovery of molybdenum and the most promising method recommended for future research and development. Membrane-based separation is the next preferred method for selective extraction of molybdenum, purification of molybdenum solutions, or co-recovery of other valuable metals.

Extraction of Molybdenum from Molybdenite Concentrates

A study on the selective solvent extraction (SX) of Molybdenum (Mo) and Rhenium (Re) from a synthetic pregnant leach solution (PLS) has been carried out using two diluents: kerosene and the ionic

Removal of molybdenum from uranium-bearing solutions Cameco

The process employs solvent extraction techniques to remove molybdenum by using a molybdenum-selective extraction reagent of the chelating hydroxy-oxime type. The molybdenum-loaded extractant is stripped with dilute alkali for reuse. Where the uranium bearing solution originates from a solvent extraction process, a pretreatment stage is applied

Extraction of molybdenum by a supported liquid membrane

by a selective flotation. Usually the processing continues by roasting the sulphide concentrate to molybdenum trioxide in a step, which is highly demanding of energy and environmentally objec-tionable due to the production of sulphur oxides. Then, leaching of molybdenite concentrates and recovery of dissolved metals by solvent extraction

(PDF) Extraction of molybdenum and nickel from

The extraction of molybdenum and nickel from a carbonaceous shale ore was investigated by oxidation roasting, followed by sulphation roasting and water leaching. the selective and efficient

Selective extraction of molybdenum from copper concentrate

Request PDF Selective extraction of molybdenum from copper concentrate by air oxidation in alkaline solution Alkaline leaching of copper concentrate bearing molybdenite was investigated.

extraction of molybdenum

May 30, 2013· A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni–Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 (D2EHPA) is an effective extractant for the extraction of molybdenum. The extraction of Mo is more than 90 % at pH

US2079805A Process for extracting molybdenum from

US2079805A US729766A US72976634A US2079805A US 2079805 A US2079805 A US 2079805A US 729766 A US729766 A US 729766A US 72976634 A US72976634 A US 72976634A US 2079805 A US2079805 A US 2079805A Authority US United States Prior art keywords ore solution sodium molybdenum wulfenite Prior art date 1934-06-09 Legal status (The legal status is an assumption and

Method of extraction of molybdenum from molybdenum

FIELD: petrochemical industry; methods of the selective extraction of molybdenum from the solutions containing molybdenum and vanadium. SUBSTANCE: the invention is pertaining to the method of the selective extraction of molybdenum from the liquid mixtures, in which molybdenum is present with vanadium at the amount of molybdenum exceeding (200) mg/l.

Extraction of molybdenum by a supported liquid membrane

by a selective flotation. Usually the processing continues by roasting the sulphide concentrate to molybdenum trioxide in a step, which is highly demanding of energy and environmentally objec-tionable due to the production of sulphur oxides. Then, leaching of molybdenite concentrates and recovery of dissolved metals by solvent extraction

Separation of vanadium and molybdenum from aqueous

Oct 24, 2019 The separation of vanadium (V) and molybdenum (VI) was studied by co-extraction with an aqueous two-phase system formed by PEG2000 + sodium sulfate + water and by selective stripping with another aqueous two-phase system formed by ammonium sulfate solution and PEG2000 phase loaded vanadium and molybdenum. The effect of aqueous pH, concentration of vanadium and molybdenum

Preparation of a New Solid-State Molybdenum-Selective

A new solid state molybdenum-selective electrode has been developed. The electrode is composed of 20% MoS 2, 60% Ag 2 S, and 20% Cu 2 S. An analytically useful potential change occurred, from 1 × 10-5 to 1 × 10-1 M molybdenum ion. The slope of the linear portion (1 × 10-1 1 × 10-5 M) was about 45 ± 2 mV/10-fold concentration changes in molybdenum. It was found that pH change between 1

SPECTROPHOTOMETRIC DETERMINATION OF MOLYBDENUM IN

INTRODUCTION: Molybdenum is the one utmost important element for many organisms and has a wide distribution throughout nature 1.Molybdenum is a bio-essential element and its occurrence in water samples is of interest from both environmental and chemical points of view 2.. Molybdenum is commercially important in metallurgical and agricultural laboratories.

(PDF) Extraction of molybdenum and nickel from

The extraction of molybdenum and nickel from a carbonaceous shale ore was investigated by oxidation roasting, followed by sulphation roasting and water leaching. the selective and efficient

Molybdenum Metallurgy Review: Hydrometallurgical Routes to

Jan 30, 2014 Solvent extraction is highly selective for recovery of molybdenum and the most promising method recommended for future research and development. Membrane-based separation is the next preferred method for selective extraction of molybdenum, purification of molybdenum solutions, or co-recovery of other valuable metals.

Molybdenum analysis IMOA

Pyrzynska, K., Determination of molybdenum in environmental samples, Analytica Chimica Acta, 2007, 590, 40-48. Water molybdenum analysis. A cloud-point extraction process using micelle of the cationic surfactant CTAB to extract Mo(VI) from aqueous solutions was investigated. The detection limit of the method was 0.1 ng mL-1.

Chemical Treatment to Recover Molybdenum and Vanadium

3.2. Effect of Time on Extraction of Vanadium and Molybdenum . A spent catalyst with 6% of caustic soda, during a period of time from 1 to 8 h, at a constant temperature of 25˚C was carried out (Figure 2). The time has a significant effect on the dissolution of molybdenum and vanadium oxides. After 4 h of leaching time, 67.3% V and 57.8%

Solvent extraction of molybdenum from acidic leach

May 30, 2013 A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni–Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 (D2EHPA) is an effective extractant for the extraction of molybdenum. The extraction of Mo is more than 90 % at pH of 0.5, contact time of 10 min, and

Process for separation of molybdenum from tungsten

Volume 23 of chamber 22 is filled with a circulating solution containing tributylphosphate as an intermediary solution for the extraction of molybdenum. The presence of the tributylphosphate or other molybdenum selective organic solution causes the selective passage of